Niacinamide

Goodvitamin

A form of Vitamin B3, it helps improve skin barrier function and reduce inflammation.

What is Niacinamide?

CAS Number

98-92-0

Formula

C6H6N2O

Molecular Weight

122.12 g/mol

Also known as: Nicotinamide, Vitamin B3, 3-Pyridinecarboxamide

What does Niacinamide do for skin?

Precursor to NAD+/NADPH coenzymes. Inhibits melanosome transfer from melanocytes to keratinocytes, reducing hyperpigmentation. Stimulates ceramide and free fatty acid synthesis in the stratum corneum, strengthening the lipid barrier. At 2-5% concentration, reduces sebum excretion rate and pore appearance.

Typical concentration: 2-10% (most clinical evidence at 4-5%)

Is Niacinamide safe?

Generally well tolerated at concentrations up to 10%. No significant adverse effects reported in clinical trials. CIR Expert Panel: safe as used in cosmetics (2005 review).

What does the research say about Niacinamide?

Regulatory Info

Status: Approved
Restrictions: 3-Pyridinecarboxamide

Can I mix Niacinamide with other ingredients?

Caution

Vitamin C

Niacinamide and vitamin C are generally safe to layer — older concerns about flushing are largely debunked at normal usage concentrations. If your skin is very sensitive, wait a few minutes between application.

Caution

AHAs (Glycolic, Lactic, etc.)

AHAs lower skin pH while niacinamide works best at neutral pH. Together they may reduce niacinamide's effectiveness. Consider using on alternate routines.

Info

Retinoids

Great combo! Niacinamide soothes inflammation and strengthens the barrier, making retinoid easier to tolerate.

Info

Hyaluronic Acid

Excellent pair! Hyaluronic acid hydrates while niacinamide strengthens the skin barrier. Use together for plump, healthy skin.

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BHAs (Salicylic Acid)

Niacinamide + salicylic acid is a power duo for oily and acne-prone skin. Niacinamide calms any irritation from the BHA.

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Ceramides

Both strengthen the skin barrier through different mechanisms. Together they're the ultimate barrier repair combo.

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Zinc (Zinc Oxide, Zinc PCA)

Niacinamide and zinc together are great for oily and acne-prone skin. They reduce sebum and calm inflammation.

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Azelaic Acid

Azelaic acid and niacinamide work synergistically for brightening. Both target hyperpigmentation through different pathways.

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Centella Asiatica (Cica)

Centella soothes while niacinamide strengthens. Together they calm redness and rebuild the skin barrier.

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Snail Mucin

Snail mucin and niacinamide are excellent together. Snail mucin hydrates and repairs while niacinamide brightens and strengthens.

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Growth Factors

PDRN/EGF pairs well with niacinamide. Both support skin repair through different pathways without any conflicts.

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Fermented Ingredients

Fermented ingredients like galactomyces enhance absorption of niacinamide. A staple K-beauty combination.

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Tranexamic Acid

Tranexamic acid and niacinamide are a brightening power duo. Both fade dark spots through different mechanisms.

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Zinc (Zinc Oxide, Zinc PCA)

Zinc + niacinamide is a classic for oily/acne-prone skin. They regulate sebum and reduce inflammation together.

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Peptides

Peptides and niacinamide both support the skin barrier and collagen. Safe and beneficial to combine.

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Arbutin

Arbutin and niacinamide are a gentle brightening duo. Both target melanin through different pathways and are safe to layer together.

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Kojic Acid

Kojic acid and niacinamide are a gentle brightening duo. Kojic acid inhibits tyrosinase while niacinamide blocks melanosome transfer — complementary pathways with no conflict.

Read all ingredient interaction guides for layering order and science-backed advice.

Frequently Asked Questions

What does Niacinamide do in skincare?+

A form of Vitamin B3, it helps improve skin barrier function and reduce inflammation. Precursor to NAD+/NADPH coenzymes. Inhibits melanosome transfer from melanocytes to keratinocytes, reducing hyperpigmentation. Stimulates ceramide and free fatty acid synthesis in the stratum corneum, strengthening the lipid barrier. At 2-5% concentration, reduces sebum excretion rate and pore appearance.

Is Niacinamide safe for sensitive skin?+

Generally well tolerated at concentrations up to 10%. No significant adverse effects reported in clinical trials. CIR Expert Panel: safe as used in cosmetics (2005 review).

What percentage of Niacinamide should I look for?+

Look for products with 2-10% (most clinical evidence at 4-5%) for clinical efficacy.

Can I use Niacinamide with Vitamin C?+

Use Niacinamide with Vitamin C carefully. Niacinamide and vitamin C are generally safe to layer — older concerns about flushing are largely debunked at normal usage concentrations. If your skin is very sensitive, wait a few minutes between application.

Can I use Niacinamide with AHAs (Glycolic, Lactic, etc.)?+

Use Niacinamide with AHAs (Glycolic, Lactic, etc.) carefully. AHAs lower skin pH while niacinamide works best at neutral pH. Together they may reduce niacinamide's effectiveness. Consider using on alternate routines.

Can I use Niacinamide with Retinoids?+

Niacinamide can be used with Retinoids. Great combo! Niacinamide soothes inflammation and strengthens the barrier, making retinoid easier to tolerate.

Can I use Niacinamide with Hyaluronic Acid?+

Niacinamide can be used with Hyaluronic Acid. Excellent pair! Hyaluronic acid hydrates while niacinamide strengthens the skin barrier. Use together for plump, healthy skin.

Further Reading